put this line in your /etc/syslog.conf :

local0.debug  /var/log/php.log

Then restart syslogd:

/etc/init.d/syslog restart

php example:

<?php
define_syslog_variables();
openlog("TextLog", LOG_PID, LOG_LOCAL0);

$data = date("Y/m/d H:i:s");
syslog(LOG_DEBUG,"Messagge: $data");

After some trial and error, I figured out what facility and priority PHP uses, which is "user.notice". So, to get your PHP errors going to a separate syslog file, put this line in your /etc/syslog.conf :

user.notice  /var/log/php.log

Then restart syslogd:

/etc/init.d/syslog restart

Why PHP uses "user" as the facility I'm not sure, probably because it's the only one that works under Windows?

Add to /etc/syslog.conf a line that says all errors from the httpd process are to go to a file called (for example) /var/log/httpd-php.log

!httpd
*.*  {tab}  /var/log/httpd-php.log

Note the tab, being a tab character! Next create a blank file to be written to. I'm sure there are 1e+6 ways to do this, but I choose

# cat > httpd-php.log << EOF
? EOF

Finally find your syslog daemon and send it a sighup to inform it of the change:

# ps ax | grep syslogd
133  ??  Ss    0:07.23 syslogd -s
# kill -1 133

man 3 syslog defines the priorities, but not the integer values. For that you'll need to read your system header file.

Let's suppose I want to log an informational message in the mail log (which happens to be true). The man page tells me I want LOG_MAIL|LOG_INFO. So I look in /usr/include/sys/syslog.h and find (this happens to be Linux, your system could be different):

#define LOG_INFO        6      /* informational */
#define LOG_MAIL        (2<<3)  /* mail system */